N-(2,4,6-Trimethylphenyl)formamide
نویسندگان
چکیده
The title compound, C(10)H(13)NO, was obtained as the unexpected, almost exclusive, product in the attempted synthesis of a manganese(I)-N-heterocyclic carbene (NHC) complex. The dihedral angle between the planes of the formamide moiety and the aryl ring is 68.06 (10)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming infinite chains along the c axis.
منابع مشابه
(2,4,6-Trimethylphenyl){2-[N-(2,4,6-trimethylphenyl)formamido]ethyl}ammonium chloride
In the title salt, C21H29N2O(+)·Cl(-), the benzene rings form a dihedral angle of 6.13 (1)°. In the crystal, N-H⋯Cl hydrogen bonds link the cations and anions into chains extending along the c axis.
متن کامل1-(3-Ammoniomethyl-2,4,6-trimethylbenzyl)-3-(2,4,6-trimethylphenyl)imidazol-1-ium dibromide monohydrate
In the title compound, C(25)H(35)N(3) (2+)·2Br(-)·H(2)O, the dihedral angles between the imidazole ring and the two outer benzene rings are 80.16 (16) and 69.40 (18)°. The component species are linked by N-H⋯Br, O-H⋯Br and C-H⋯Br hydrogen bonds.
متن کاملN-(2,4,6-Trimethylphenyl)succinamic acid
The amide bond in the title compound {systematic name: 3-[(2,4,6-trimethyl-phen-yl)amino-carbon-yl]propionic acid}, C(13)H(17)NO(3), has a trans conformation. In the crystal, two mol-ecules form a centrosymmetric dimer connected by pairs of O-H⋯O hydrogen bonds. Inter-molecular N-H⋯O hydrogen bonds link the dimers into a three dimensional network.
متن کامل1-Ethyl-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate
The title compound, C(14)H(19)N(2) (+)·BF(4) (-), was obtained by reaction of 1-ethyl-3-(2,4,6-trimethyl-phen-yl)imidazolium tetra-fluoro-borate with sodium tetra-fluoro-borate. The imidazole ring makes a dihedral angle of 78.92 (13)° with the benzene ring.
متن کاملDibromidobis[1-(2,4,6-trimethylphenyl)-1,4,5,6-tetrahydropyrimidine-κN 3]palladium(II)
In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra-hydro-pyrimidine group of the N-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C-N-Pd-Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related str...
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